Page 9 - i1052-5173-27-7
P. 9

CONCLUSIONS                                           Carpenter, P.K., 2016, Compositional stage                  LIBS analyses on Mars using the LIBSSIM
                                                         mapping by EPMA and micro-XRF: Microscopy                program: Planetary and Space Science, v. 81,
  Our models show quantitatively what is                 and Microanalysis, v. 22, p. 94–95, doi: 10.1017/        p. 48–54, doi:10.1016/j.pss.2013.03.004.
intuitively obvious: heterogeneous rocks                 S143192761600132X.                                    Mysen, B.O., and Richet, P., 2005, Silicate Glasses
with coarse grain sizes present great chal-                                                                       and Melts: Properties and Structure: San Diego,
lenges when obtaining bulk analyses. Care             Carpenter, P.K., North, S.N., Jolliff, B.L., and            Elsevier Inc., 560 p.
must be taken both when choosing ran-                    Donovan, J.J., 2013, EPMA quantitative                Nutman, A.P., Mojzsis, S.J., and Friend, C.R.L.,
domly distributed analytical points and                  compositional mapping and analysis of lunar              1997, Recognition of ≥3850 Ma water-lain
when interpreting data from instruments                  samples: Lunar and Planetary Institute, 44th             sediments in West Greenland and their
with different sampling volumes (Fig. 6).                Lunar and Planetary Science Conference,                  significance for the early Archaean Earth:
Moreover, rocks with visible texture (lay-               abstract 1827.                                           Geochimica et Cosmochimica Acta, v. 61,
ering, phenocrysts, etc.) must be carefully                                                                       p. 2475–2484, doi:10.1016/S0016-7037(97)
sampled (if bulk compositions are needed)             Chayes, F., 1956, Petrographic Modal Analysis: An           00097-5.
to ensure that analysis locations are pro-               Elementary Statistical Appraisal: New York,           Philpotts, A.R., and Ague, J., 2009, Principles of
portionally representative of all textures               John Wiley & Sons, 113 p.                                Igneous and Metamorphic Petrology: Cambridge,
present (Fig. 6). Additionally, the ratio of                                                                      Cambridge University Press, 686 p., doi:10.1017/
sample size to analytical size needs to be            Cox, K.G., Bell, J.D., and Pankhurst, R.J., 1979,           CBO9780511813429.
considered, especially as modern instru-                 The Interpretation of Igneous Rocks: London,          Potts, P.J., Bowles, J.F.W., Reed, S.J.B., and Cave,
ments resolve increasingly small analytical              George Allen & Unwin, 450 p., doi:10.1007/978-           M.R., editors, 1995, Microprobe Techniques in
volumes. The concept of a “bulk analysis”                94-017-3373-1.                                           the Earth Sciences: London, Chapman & Hall,
likely needs to be revised for each system,                                                                       430 p., doi: 10.1007/978-1-4615-2053-5.
following the methods provided in this                Daly, R.A., 1933, Igneous Rocks and the Depths of        Powell, R., Holland, T.J.B., and Worley, B., 1998,
study (Fig. 6).                                          the Earth: New York, Hafner Publishing                   Calculating phase diagrams involving solid
                                                         Company, 598 p.                                          solutions via non-linear equations, with
ACKNOWLEDGMENTS                                                                                                   examples using THERMOCALC: Journal of
                                                      Dyar, M.D., McCanta, M.C., Breves, E., Carey,               Metamorphic Geology, v. 16, p. 577–588,
   We acknowledge funding from NSF grants                C.J., and Lanzirotti, A., 2016, Accurate                 doi:10.1111/j.1525-1314.1998.00157.x.
EAR-1219850 (MCM) and EAR-1219761 (MDD).                 predictions of iron redox state in silicate glasses:  Valley, J.W., Reinhard, D.A., Cavosie, A.J.,
Reviews from two anonymous reviewers were                A multivariate approach using X-ray absorption           Ushikubo, T., Lawrence, D.F., Larson, D.J.,
thorough and strengthened this paper.                    spectroscopy: American Mineralogist, v. 101,             Kelly, T.F., Snoeyenbos, D.R., and Strickland,
                                                         p. 744–747.                                              A., 2015, Nano- and micro-geochronology in
REFERENCES CITED                                                                                                  Hadean and Archean zircons by atom-probe
                                                      Garvie, L.A.J., and Buseck, P.R., 1998, Ratios of           tomography and SIMS: New tools for old
Asimow, P.D., 2000, Melting of the mantle, in            ferrous to ferric iron from nanometre-sized areas        minerals: The American Mineralogist, v. 100,
   Sigurdsson, H., Houghton, B., McNutt, S.R.,           in minerals: Nature, v. 396, p. 667–670,                 p. 1355–1377, doi:10.2138/am-2015-5134.
   Rymer, H., and Stix, S., eds., Encyclopedia           doi:10.1038/25334.                                    van Aken, P., and Liebscher, B., 2002,
   of Volcanoes: San Diego, Academic Press,                                                                       Quantification of ferrous/ferric ratios in minerals:
   p. 55–68.                                          Kelly, T.F., and Larson, D.J., 2012, Atom Probe             new evaluation schemes of Fe L23 electron
                                                         Tomography 2012: Annual Review of Materials              energy-loss near-edge spectra: Physics and
Baker, M.B., Grove, T.L., and Price, R., 1994,           Research, v. 42, p. 1–31, doi:10.1146/annurev-           Chemistry of Minerals, v. 29, p. 188–200,
   Primitive basalts and andesites from the Mt.          matsci-070511-155007.                                    doi:10.1007/s00269-001-0222-6.
   Shasta region, N. California: Products of varying                                                           Yoder, H.S., Jr., and Tilley, C.E., 1962, Origin of
   melt fraction and water content: Contributions to  Kilinc, A., Carmichael, I.S.E., Rivers, M.L., and           basaltic magmas: An experimental study of natural
   Mineralogy and Petrology, v. 118, p. 111–129,         Sack, R.O., 1983, The ferrous-ferric ratio of            and synthetic rock systems: Journal of Petrology,
   doi:10.1007/BF01052863.                               natural silicate liquids equilibrated in air:            v. 3, p. 342–532, doi:10.1093/petrology/
                                                         Contributions to Mineralogy and Petrology,
Basaltic Volcanism Study Project, 1981, Basaltic         v. 83, p. 136–140.                                       3.3.342.
   Volcanism on the Terrestrial Planets: New York,
   Pergamon Press Inc., 1286 p.                       Kress, V., and Carmichael I.S.E., 1991, The              MANUSCRIPT RECEIVED 7 MAR. 2016
                                                         compressibility of silicate liquids containing
Bowen, N.L., 1928, The Evolution of the Igneous          Fe2O3 and the effect of composition,                  REVISED MANUSCRIPT RECEIVED 25 OCT. 2016
   Rocks: Princeton, New Jersey, Princeton               temperature, oxygen fugacity, and pressure on
   University Press, 334 p.                              their redox states: Contributions to Mineralogy       MANUSCRIPT ACCEPTED 1 DEC. 2016
                                                         and Petrology, v. 108, p. 82–92.
Bucher, K., and Frey, M., 2002, Petrogenesis of
   Metamorphic Rocks: Heidelberg, Springer-           Martin, J.W., 2003, The Local Chemical Analysis
   Verlag, 440 p., doi: 10.1007/978-3-662-04914-3.       of Materials: London, Elsevier, 234 p.

                                                      McCanta, M.C., Rutherford, M.J., and Hammer,
                                                         J.E., 2007, Pre-eruptive and syn-eruptive
                                                         conditions in the Black Butte, California dacite:
                                                         Insight into crystallization kinetics in a silicic
                                                         magma system: Journal of Volcanology and
                                                         Geothermal Research, v. 160, p. 263–284,
                                                         doi:10.1016/j.jvolgeores.2006.10.004.

                                                      McCanta, M.C., Dobosh, P.A., Dyar, M.D., and
                                                         Newson, H.E., 2013, Testing the veracity of

                                                      www.geosociety.org/gsatoday                                                                                       9
   4   5   6   7   8   9   10   11   12   13   14